Billy Bob Thornton and Angelina Jolie have divorced.
(5 May 2000 - 27 May 2003) (divorced)
Angelina’s second marriage was to Billy Bob looked like he was going to offer Angelina the stability & love. The pair adopted adorable Cambodian orphan Maddox. But it turned out that Billy Bob wasn’t... exactly the paternal type and they divorced in 2003.