Alessandra Ambrosio and her husband, Jamie Mazur, who owns a denim company, met at a mutual friend's wedding in Rio de Janeiro. But they didn't start dating until two years later, when they ran into each other at Coachella. Ambrosio says of Mazur: "I always have new jeans, and because he has to follow trends, I get the best gifts — like Louboutins and vintage sunglasses. One Valentine's Day, he learned all my favorite Pearl Jam songs and serenaded me."
Ambrosio has been engaged to businessman Jamie Mazur, founder of RE/DONE jeans, since 2008 and they have two children, Anja Louise (b. 2008) and Noah Phoenix (b. 2012), both born in Florianópolis. Alessandra also holds a very active Facebook page in which she posts personal and professional photos as well as many motivational and inspirational quotes either through captions or through dedicated posts, thus securing over three million fans on the social media site.